How Experimental Reproducibility Affects Our Effort to Combat Climate Change
DOI:
https://doi.org/10.47611/jsrhs.v11i3.2984Keywords:
adsorption, data analysisAbstract
I present the comparison of CO2 adsorption data on ZIF-8 to show the differences in the data measured by different researchers. I used an isotherm model to fit the collected adsorption data using a simple Least Squares method using Microsoft Excel solver function. The model describes the adsorption data very well and the collected data show quite a large spread with outliers. The heat of adsorption calculated from the adsorption data also shows a very large spread. This level of spread in experimental data can lead to incorrect calculations when these data are used in large scale applications, such as gas separations or gas capture where adsorption is widely studied for uses. Through this work, I highlight the importance of producing reproducible experimental measurements that compare well with the data measured by other researchers.
Downloads
References or Bibliography
Thommes, M., Kaneko, K., Neimark, A. V., Olivier, J. P., Rodriguez-Reinoso, F., Rouquerol, J., & Sing, K. S. W. (2015). Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC technical report). Pure and Applied Chemistry, 87(9-10), 1051-1069. https://doi.org/10.1515/pac-2014-1117
Britannica, T. Editors of Encyclopaedia (2013, August 16). silica gel. Encyclopedia Britannica. https://www.britannica.com/science/silica-gel
U.S. Energy Information Administration - independent statistics and analysis. U.S. energy facts explained - consumption and production - U.S. Energy Information Administration (EIA). (2021). Retrieved May 25, 2022, from https://www.eia.gov/energyexplained/us-energy-facts/
Geiger, B. (2019, December 3). The heat that keeps on giving. Science News for Students. Retrieved May 25, 2022, from https://www.sciencenewsforstudents.org/article/heat-keeps-giving
Sholl, D. S. & Lively, R. P. (2016). Seven chemical separations to change the world. Nature, 532, 435-437. https://www.nature.com/articles/532435a
Nancy W. S. MIT Energy Initiative. (2020). A new approach to carbon capture. MIT News. Massachusetts Institute of Technology. Retrieved May 25, 2022, from https://news.mit.edu/2020/new-approach-to-carbon-capture-0709
Nguyen, H. G., Espinal, L., van Zee, R. D., Thommes, M., Toman, B., Hudson, M. S., Mangano, E., Brandani, S., Broom, D. P., Benham, M. J., Cychosz, K., Bertier, P., Yang, F., Krooss, B. M., Siegelman, R. L., Hakuman, M., Nakai, K., Ebner, A. D., Erden, L., … De Weireld, G. (2018). A reference high-pressure CO2 adsorption isotherm for ammonium ZSM-5 zeolite: Results of an interlaboratory study. Adsorption, 24(6), 531–539. https://doi.org/10.1007/s10450-018-9958-x
Banerjee, R., Phan, A., Wang, B., Knobler, C., Furukawa, H., O'Keeffe, M., & Yaghi, O. M. (2008). High-throughput synthesis of zeolitic imidazolate frameworks and application to CO2 capture. Science, 319(5865), 939–943. https://doi.org/10.1126/science.1152516
Czepirski, L. & Jagiello, J. (1989). Virial-type thermal equation of gas - solid adsorption. Chemical Engineering Science, 44(4), 797–801. https://doi.org/10.1016/0009-2509(89)85253-4
Venna, S. R. & Carreon, M. A. (2009). Highly permeable zeolite imidazolate framework-8 membranes for CO2/CH4 separation. Journal of the American Chemical Society, 132(1), 76–78. https://doi.org/10.1021/ja909263x
Xu, G., Yao, J., Wang, K., He, L., Webley, P. A., Chen, C.-sheng, & Wang, H. (2011). Preparation of zif-8 membranes supported on ceramic hollow fibers from a concentrated synthesis gel. Journal of Membrane Science, 385-386, 187–193. https://doi.org/10.1016/j.memsci.2011.09.040
Huang, H., Zhang, W., Liu, D., Liu, B., Chen, G., & Zhong, C. (2011). Effect of temperature on gas adsorption and separation in ZIF-8: A combined experimental and molecular simulation study. Chemical Engineering Science, 66(23), 6297–6305. https://doi.org/10.1016/j.ces.2011.09.009
Chen, C., Kim, J., Yang, D.-A., & Ahn, W.-S. (2011). Carbon dioxide adsorption over zeolite-like Metal Organic Frameworks (zmofs) having a sod topology: Structure and ion-exchange effect. Chemical Engineering Journal, 168(3), 1134–1139. https://doi.org/10.1016/j.cej.2011.01.096
Ito, M., Nishihara, H., Yamamoto, K., Itoi, H., Tanaka, H., Maki, A., Miyahara, M. T., Yang, S. J., Park, C. R., & Kyotani, T. (2013). Reversible pore size control of elastic microporous material by Mechanical Force. Chemistry - A European Journal, 19(39), 13009–13016. https://doi.org/10.1002/chem.201301806
Sun, W., Lin, L.-C., Peng, X., & Smit, B. (2014). Computational screening of porous metal-organic frameworks and zeolites for the removal of SO2 and NOx from flue gases. AIChE Journal, 60(6), 2314–2323. https://doi.org/10.1002/aic.14467
Greenhouse gas reporting program: Industrial profile: Power plants sector. U.S. Environmental Protection Agency. (2019, September). Retrieved May 28, 2022, from https://www.epa.gov
Published
How to Cite
Issue
Section
Copyright (c) 2022 Minjae Baek; Younmi Kim
This work is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License.
Copyright holder(s) granted JSR a perpetual, non-exclusive license to distriute & display this article.